APPLIED HYDROCARBON THERMODYNAMICS EDMISTER PDF

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APPLIED HYDROCARBON THERMODYNAMICS EDMISTER PDF

For processing fossil fuels toward thermal and chemical products, economic design requires quantitative information on phase-equilibrium properties for hydrocarbon-water systems. Two hydrocarbon water phase-equilibrium problems are studied in this thesis. The first study presents experimental measurements for liquid-liquid mutual solubilities and vapor pressures of aqueous mixtures containing aromatic hydrocarbons at high temperatures under conditions of three-phase vapor-liquid-liquid equilibrium. An apparatus has been constructed in which the phases are equilibrated, sampled and analyzed using gas-liquid chromatography. The second study presents a new correlation for the inhibition effect of methanol on hydrate formation in moist natural gas mixtures applicable between and K. Methanol is commonly used to inhibit hydrate formation by lowering the fugacity of water in coexisting phases. Six phases are potentially present in these mixtures: gas, aqueous liquid, hydrocarbon liquid, ice, and hydrate structures I and II.

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Applied Hydrocarbon Thermodynamics

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